Hebei
Messi Biology Co., Ltd. prepared and modified flaky magnesium oxide
powder and used it as an inorganic filler. Through experiments and
simulation studies, the purpose is to improve the room temperature and
high temperature energy storage density of PVDF-based and PEI-based
composite materials. , the paper makes a preliminary analysis of the
reasons for the performance improvement, and the main research contents
are as follows.
The flaky magnesium oxide powder was prepared by hydrothermal synthesis method combined with calcination treatment. Taking the breakdown field strength of the composite material as the target, the optimal hydrothermal time and ammonia concentration of the flaky magnesium oxide powder were obtained by optimizing the single factor test method. , 24h and 20wt.%, respectively, the prepared MgO powder was flake-like, with a lateral dimension of about 400nm and a thickness of about 40nm. When the powder addition amount was 2.8wt.%, the room temperature energy storage density of the prepared flaky magnesium oxide/PVDF composite material reached 16.9J/cm3, exceeding 80% of the PVDF matrix, indicating that the flaky magnesium oxide was helpful to increase the energy storage density of the material.
Taking PEI as the matrix, the effect of adding flaky magnesium oxide powder on the energy storage density of PEI-based composites with temperature was studied. When it is 3.4wt.% magnesia, the energy storage density of magnesia/PEI composite material is better at 25 ℃ and 150 ℃, which are 5.54J/cm3 and 3.79J/cm3, respectively, because of the compatibility between magnesia and PEI matrix Poor, resulting in a significant decrease in the breakdown field strength with increasing temperature.
For this reason, the silane coupling agent KH550 was used to modify the surface of the flaky magnesium oxide powder, and the optimal content of the modifier was determined by the single factor test method as m(KH550):m(magnesia)=3: 100, when adding 3.0wt.% modified flaky m-magnesia, the energy storage density of m-magnesia/PEI composites can reach 6.10J/cm3 and 5.18J/cm3 at 25℃ and 150℃ cm3, respectively increased by 10% and 8% compared with before modification, indicating that KH550 is an effective modifier for improving the energy storage density and temperature stability of MgO/PEI composites. The reason is that…
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